Hi,
I'm not sure but the duplication of Calendar, Contacts, etc. could be because if I'm not mistaken you have the same Outlook.pst file attached from two different locations (from C: and N:) and probably in different stages. I'm wrong about this?
The Compress and Export options reorganize the pst file and reduce the file usage, its possible the program leave some room prepared to receive new data to avoid a constant resizing of the file.